Synthesis of the novel chiral catalysts by click chemistry and their application

被引：5

作者：

Li, Qian ^{[1
]}

Li, Le ^{[1
]}

Pei, Wenbo ^{[1
]}

Wang, Shanwei ^{[1
]}

Zhang, Zhengpu ^{[1
]}

机构：

[1] Nankai Univ, Inst Polymer Chem, Key Lab Funct Polymer Mat, Minist Educ, Tianjin 300071, Peoples R China

来源：

SYNTHETIC COMMUNICATIONS | 2008年 / 38卷 / 09期

关键词：

asymmetric alkylations; cinchona alkoloids; click reaction; phase-transfer catalysis;

D O I：

10.1080/00397910801914020

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Novel cinchonine ammonium salt derivatives have been prepared by 1,3-dipolar cycloaddition. Their chiral catalytic efficacy was investigated in the asymmetric alkylation of N-diphenylmethyleneglycine t-butyl ester in the water phase. As the special structure of the catalyst, its asymmetric alkylation catalytic behavior both in organic solvents and in water is satisfactory, which is environmentally friendly.

引用

页码：1470 / 1477

页数：8

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