Luminescence, adsorption and topological analysis of a new two-fold interpenetrating 3D Cd(II) coordination polymer based on a tetracarboxylate ligand

被引：12

作者：

Yuan, Fei ^{[1
,2
]}

Yuan, Chun-Mei ^{[1
]}

Hu, Huai-Ming ^{[2
]}

Wang, Ting-Ting ^{[2
]}

Zhou, Chun-Sheng ^{[1
]}

机构：

[1] Shangluo Univ, Coll Chem Engn & Modern Mat, Shaanxi Key Lab Comprehens Utilizat Tailings Reso, Shangluo 726000, Peoples R China

[2] Northwest Univ, Coll Chem & Mat Sci, Minist Educ, Key Lab Synthet & Nat Funct Mol Chem, Xian 710127, Shaanxi, Peoples R China

来源：

POLYHEDRON | 2018年 / 139卷

关键词：

Microporous coordination polymer; Carboxylate ligand; Adsorption; Luminescence; Topology; METAL-ORGANIC FRAMEWORK; SENSOR;

D O I：

10.1016/j.poly.2017.10.034

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A new 3D microporous coordination polymer [Cd(H2BTTB)](n)center dot 0.5nH(2)O (1), (H4B'TTB =4,4',4 '',4 '''-benzene-1,2,4,5-tetrayltetrabenzoic acid), was constructed under solvothermal condition and structurally characterized by elemental analysis, FT-IR spectroscopy, powder X-ray diffraction (PXPD) and thermogravimetric analyses (TGA). Single crystal X-ray diffraction indicates that compound 1 displays a two -fold interpenetrating dinodal (4,4) -connected three-dimensional coordination network with the PtS topological net and the point symbol of {4(2).8(4)}. Furthermore, photoluminescence and adsorption of 1 were investigated. (C) 2017 Elsevier Ltd. All rights reserved.

引用

页码：257 / 261

页数：5

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