Mechanism and kinetics of methanol synthesis coupled with water-gas shift reaction.

被引：0
|
作者：
Lin, GI [1 ]
Kotyaev, KP [1 ]
Rozovskii, AY [1 ]
机构：
[1] Russian Acad Sci, AV Topchiev Petrochem Synth Inst, Moscow 117912, Russia
来源：
KINETICS AND CATALYSIS | 1998年 / 39卷 / 06期
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D O I：
暂无
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
The experimental data are reported on the kinetics of methanol synthesis and water-gas shift reaction. Under certain conditions of methanol synthesis, some anomalous kinetics was observed: an increase in the average rate of the reaction in the integral flow-type reactor with an increase in the contact time. This unusual behavior is stipulated by the coupling of methanol synthesis with the water-gas shift reaction. A modified scheme of the mechanism is proposed that accounts for this coupling.
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页码：798 / 802
页数：5
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