High-resolution rotational analysis of HDS:: 2v3, v2+2v3, 3v3, and v2+3v3 bands

被引：5
|
作者：
Liu, AW
Gao, B
Cheng, GS
Qi, F
Hu, SM [1 ]
机构：
[1] Univ Sci & Technol China, Dept Phys Chem, Hefei Natl Lab Phys Sci Mircoscale, Anhua 230026, Peoples R China
[2] Univ Sci & Technol China, Natl Synchrotron Radiat Lab, Hefei 230027, Peoples R China
来源：
JOURNAL OF MOLECULAR SPECTROSCOPY | 2005年 / 232卷 / 02期
基金：
中国国家自然科学基金;
关键词：
vibration-rotation spectroscopy; HDS molecule; spectroscopic parameters;
D O I：
10.1016/j.jms.2005.04.016
中图分类号：
O64 [物理化学（理论化学）、化学物理学]; O56 [分子物理学、原子物理学];
学科分类号：
070203 ; 070304 ; 081704 ; 1406 ;
摘要：
High-resolution Fourier transform spectrum of the (HDS)-S-32 molecule was studied in the region of 5000-9000 cm(-1). More than 1600 observed transitions yielded 239, 264, 131, and 116 upper state ro-vibrational energies of the states (002), (012), (003), and (013), respectively. With a Watson-type effective Hamiltonian model, the ro-vibrational parameters of these four upper states were determined by a least-square fitting which can reproduce the ro-vibrational energies close to the experimental accuracy. The relative linestrengths are also discussed. (c) 2005 Elsevier Inc. All rights reserved.
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收藏
页码：279 / 290
页数：12
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