BrOsted acid-catalyzed electrophilic trifluoromethylthiolation of indoles using thermally stable trifluoromethylthiolating reagent

被引：48
|
作者：
Ma, Bingqing [1 ]
Shao, Xinxin [1 ]
Shen, Qilong [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, Key Lab Organofluorine Chem, Shanghai 200032, Peoples R China
来源：
JOURNAL OF FLUORINE CHEMISTRY | 2015年 / 171卷
基金：
中国国家自然科学基金;
关键词：
Fluorine; Trifluoromethylthioindole; BrOsted acid; ARYL BORONIC ACIDS; HYPERVALENT IODINE REAGENT; OXIDATIVE TRIFLUOROMETHYLTHIOLATION; TRIFLUOROMETHANESULFANYLATION; ALKYNES; AMINES; MILD;
D O I：
10.1016/j.jfluchem.2014.09.011
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
A BrOsted acid-catalyzed electrophilic trifluoromethylthiolation of indoles under mild conditions is described. The reaction was insensitive to moisture and oxygen, that should allow for easy handling. In addition, the reaction is compatible with a variety of functional groups. (C) 2014 Elsevier B.V. All rights reserved.
引用
收藏
页码：73 / 77
页数：5
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