The Magnetic properties of Mn0.3Mg0.2Zn0.5Fe2O4 and Mn0.3Mg0.2Co0.5Fe2O4: The effect of milling

被引:0
|
作者
Dlamini, W. B. [1 ]
Msomi, J. Z. [1 ]
Moyo, T. [1 ]
机构
[1] Univ KwaZulu Natal, Sch Chem & Phys, Westville Campus,P Bag X54001, ZA-4000 Durban, South Africa
关键词
Ferrites; Nanoparticles; Mossbauer spectroscopy; Magnetization; NANOFERRITES; SIZE;
D O I
10.1016/j.phpro.2015.12.173
中图分类号
O59 [应用物理学];
学科分类号
摘要
Mn0.3Mg0.2Zn0.5Fe2O4 and Mn0.3Mg0.2Co0.5Fe2O4 nanoparticles with particle diameters of about 13 nm were synthesized by glycol-thermal method. The as-prepared specimens were then milled at different times up to 50 h and the single phase spinel structure confirmed by X-ray diffraction. The properties for the as-prepared and milled samples for the two systems were deduced and contrasted. Significant changes induced by milling in particle size, magnetization, coercive field and hyperfine parameters are reported. Fe-57 Mossbauer spectra at room temperature show ordered magnetic spin states in both Mn0.3Mg0.2Zn0.5Fe2O4 and Mn0.3Mg0.2Co0.5Fe2O4 by magnetization measurements.
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页码:1041 / 1049
页数:9
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