Intramolecular propargyl transfer reaction catalyzed by electrogenerated nickel complexes

被引：7

作者：

Franco, D ^{[1
]}

Duñach, E ^{[1
]}

机构：

[1] Univ Nice, CNRS, Lab Chim Mol, F-06108 Nice 2, France

来源：

TETRAHEDRON LETTERS | 1999年 / 40卷 / 15期

关键词：

nickel; electrochemical; intramolecular; propargyl ether; aldehyde;

D O I：

10.1016/S0040-4039(99)00357-3

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The intramolecular transfer of the propargyl group of aryl propargyl ethers to a carbonyl group can be effected by a nickel-catalyzed electrochemical reaction. Homopropargyl alcohols with 2-hydroxyphenyl substituents can be obtained, using a magnesium anode in single compartment cells. (C) 1999 Elsevier Science Ltd. All rights reserved.

引用

页码：2951 / 2954

页数：4

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