Performance of palladium-containing supported catalysts in the oxidation of 1-butene

被引：2
|
作者：
Liu, SL [1 ]
Xu, LY [1 ]
Xie, SJ [1 ]
Wang, QX [1 ]
机构：
[1] Chinese Acad Sci, Dalian Inst Chem Phys, Lab Nat Gas Utilizat & Appl Catalysis, Dalian 116023, Peoples R China
来源：
REACTION KINETICS AND CATALYSIS LETTERS | 2003年 / 79卷 / 02期
关键词：
oxidation of 1-butene; butanone; propionic acid; palladium-containing supported catalysts;
D O I：
10.1023/A:1024586102347
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Performance of palladium-containing supported catalysts in the oxidation of 1-butene was investigated in a fixed-bed flow microreactor. The Pd-Fe-HCl/Ti-Al catalyst is the best among the five Pd-Fe-HCl/X (A = SiO2, gamma-Al2O3, Al-Ti, TiO2, MCM-22) catalysts for the oxidation of I-butene to butanone. It is interesting that high propionic acid selectivity can be obtained when V and H2SO4 are added to the palladium-containing supported catalysts.
引用
收藏
页码：281 / 286
页数：6
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