Poly(ether ketone azomethane)s and poly(ether ketone imide)s containing naphthylene moieties

被引：7
|
作者：
Zhu, Ming [1 ]
Liu, Xiao [1 ]
Liu, Baijun [1 ]
Jiang, Zhenhuan [1 ]
Matsumoto, Toshihiko [2 ]
机构：
[1] Jilin Univ, Alan G MacDiarmid Inst, Changchun 130012, Peoples R China
[2] Tokyo Polytech Univ, Ctr Nano Sci & Technol, Kanagawa 2430297, Japan
来源：
POLYMER BULLETIN | 2011年 / 67卷 / 09期
基金：
中国国家自然科学基金;
关键词：
High-performance polymer; Polyetherketone; Polyimide; Polyazomethine; Solubility; POLY(ARYL ETHER KETONE)S; POLYAZOMETHINES; STABILITY;
D O I：
10.1007/s00289-011-0488-x
中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
A new diamine monomer, 1,5-bis[4-(4-aminophenoxy)]benzoyl-2,6-dimethoxynaphthalene, was synthesized via a Friedel-Crafts acylation reaction followed by an aromatic nucleophilic substitution reaction. Six ether-ketone linked polymers, named as poly(ether ketone azomethane)s and poly(ether ketone imide)s, were successfully prepared through the polycondensations of the diamine monomer with dialdehydes and dianhydrides, respectively. These naphthylated polymers exhibited high T (g) values (142-288 A degrees C), due to their bulky and rigid chemical structure. Meanwhile, they showed good thermal stability and improved solubility. Typically, some of them were casted into thin flexible film and showed high moduli.
引用
收藏
页码：1761 / 1771
页数：11
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