The development and application of chiral trisoxazolines in asymmetric catalysis and molecular recognition

被引:125
|
作者
Zhou, J [1 ]
Tang, Y [1 ]
机构
[1] Shanghai Inst Organ Chem, State Key Lab Organomet Chem, Shanghai 200032, Peoples R China
关键词
D O I
10.1039/b408712g
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
The development of suitable ligands that upon coordination to a metal facilitate enantioselective reactions or are able to selectively recognize a molecule are fundamental endeavours in organic chemistry. Chiral ligands that contain one or two oxazoline groups have been extensively studied and applied successfully to many metal catalyzed reactions. Accordingly, the development and application of chiral trisoxazolines has received increasing attention in the last decade. This tutorial review covers the synthetic methods for the preparation of chiral trisoxazolines, the application of chiral trisoxazolines in asymmetric catalysis and molecular recognition.
引用
收藏
页码:664 / 676
页数:13
相关论文
共 50 条
  • [1] Function and Application of Supramolecular Gels Chiral Molecular Recognition and Asymmetric Catalysis
    Jin Qingxian
    Li Jing
    Li Xiaogang
    Zhang Li
    Fang Shaoming
    Liu Minghua
    PROGRESS IN CHEMISTRY, 2014, 26 (06) : 919 - 930
  • [2] Development and application of chiral spirocyclic phosphoric acids in asymmetric catalysis
    Rahman, Abdul
    Lin, Xufeng
    ORGANIC & BIOMOLECULAR CHEMISTRY, 2018, 16 (26) : 4753 - 4777
  • [3] Molecular motion and molecular recognition between chiral and prochiral molecules in asymmetric heterogeneous catalysis
    Goubert, Guillaume
    Demers-Carpentier, Vincent
    Masini, Federico
    Rasmussen, Anton M. Havelund
    Hammer, Bjork
    McBreen, Peter H.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2012, 243
  • [4] CHIRAL RECOGNITION AND ASYMMETRIC CATALYSIS WITH METAL PORPHYRINS
    Simonneaux, Gerard
    Srour, Hassan
    Le Maux, Paul
    Chevance, Soizic
    SYMMETRY-CULTURE AND SCIENCE, 2014, 25 (02): : 121 - 124
  • [5] Molecular Recognition in Asymmetric Counteranion Catalysis: Understanding Chiral Phosphate-Mediated Desymmetrization
    Duarte, Fernanda
    Paton, Robert S.
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2017, 139 (26) : 8886 - 8896
  • [6] Molecular Recognition in Asymmetric Counteranion Catalysis: Understanding Chiral Phosphate-Mediated Desymmetrization
    Duarte, Fernanda (fernanda.duarte@ed.ac.uk), 1600, American Chemical Society (139):
  • [7] Application of chiral pincer complexes in asymmetric catalysis
    Szabo, Kalman J.
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 2009, 238
  • [8] Application of chiral recyclable catalysts in asymmetric catalysis
    Han, Guiping
    Ren, Wenqi
    Zhang, Shengyong
    Zuo, Zhenyu
    He, Wei
    RSC ADVANCES, 2024, 14 (23) : 16520 - 16545
  • [9] Synthesis of chiral cyrhetrenes and their application in asymmetric catalysis
    Bolm, C
    Xiao, L
    Hintermann, L
    Focken, T
    Raabe, G
    ORGANOMETALLICS, 2004, 23 (10) : 2362 - 2369
  • [10] Application of Chiral Olefin Ligands in Asymmetric Catalysis
    Feng, Xiangqing
    Du, Haifeng
    CHINESE JOURNAL OF ORGANIC CHEMISTRY, 2015, 35 (02) : 259 - 272