Lanthanum chromite materials as potential symmetrical electrodes for solid oxide fuel cells

被引:38
|
作者
Ruiz-Morales, J. C. [1 ]
Lincke, H.
Marrero-Lopez, D.
Canales-Vazquez, J.
Nunez, P.
机构
[1] Univ La Laguna, Dept Inorgan Chem, Tenerife 38200, Canary Island, Spain
[2] Renewable Energy Res Inst, Albacete 02006, Spain
关键词
solid oxide fuel cell; symmetrical electrodes; interconnector; YSZ; chromites;
D O I
10.3989/cyv.2007.v46.i4.240
中图分类号
TQ174 [陶瓷工业]; TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
A commonly used interconnector material has been tested as electrode for a new concept of Solid Oxide Fuel Cell, where the same material could be used, simultaneously, as interconnector, anode and cathode. We have found that a typical substituted chromite, such as La0.7Ca0.3CrO3-delta (LCC) can be considered a good candidate for such configuration, due to its high electronic conductivity in both reducing and oxidising conditions, and moderate catalytic properties for oxygen reduction and hydrogen oxidation. The symmetrical design renders performances of 100 mWcm(-2) at 950 degrees C, using 0, and H, as oxidant and fuel respectively. Performances exceeding 300 mWcm(-2) can be predicted for a 100 mu m-thick YSZ electrolyte.
引用
收藏
页码:218 / 223
页数:6
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