A mechanistic study of low temperature CO oxidation over cobalt oxide

被引：98
|
作者：
Jansson, J [1 ]
Skoglundh, M [1 ]
Fridell, E [1 ]
Thormählen, P [1 ]
机构：
[1] Chalmers Univ Technol, Competence Ctr Catalysis, SE-41296 Gothenburg, Sweden
来源：
TOPICS IN CATALYSIS | 2001年 / 16卷 / 1-4期
关键词：
CO oxidation; low temperature; in situ FTIR; cobalt oxide; deactivation;
D O I：
10.1023/A:1016681620216
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
The CO oxidation over Co3O4 and Co3O4/Al2O3 has been investigated using flow reactor and in situ FTIR studies. Cobalt oxide shows very high activity even at room temperature. However, a gradual deactivation takes place during reaction. The deactivated catalyst shows the presence of two different carbonate species and one graphite-like species. A possible mechanism for the deactivation is discussed.
引用
收藏
页码：385 / 389
页数：5
相关论文
共 50 条
  • [1] A Mechanistic Study of Low Temperature CO Oxidation over Cobalt Oxide
    Jonas Jansson
    Magnus Skoglundh
    Erik Fridell
    Peter Thormählen
    Topics in Catalysis, 2001, 16-17 : 385 - 389
  • [2] Low-temperature CO oxidation over platinum and cobalt oxide catalysts
    Thormählen, P
    Skoglundh, M
    Fridell, E
    Andersson, B
    JOURNAL OF CATALYSIS, 1999, 188 (02) : 300 - 310
  • [3] A mechanistic study of the low-temperature conversion of carbon monoxide to carbon dioxide over a cobalt oxide catalyst
    Pollard, Matthew J.
    Weinstock, B. Andre
    Bitterwolf, Thomas E.
    Griffiths, Peter R.
    Newbery, A. Piers
    Paine, John B., III
    JOURNAL OF CATALYSIS, 2008, 254 (02) : 218 - 225
  • [4] Low temperature CO oxidation over Fe-Co mixed oxide nanocatalysts
    Biabani-Ravandi, Abolfazi
    Rezaei, Mehran
    CHEMICAL ENGINEERING JOURNAL, 2012, 184 : 141 - 146
  • [5] Low Temperature CO Oxidation over Cobalt Catalysts Supported on Mesoporous CeO2
    Tian, Junjie
    Na, Wei
    Wang, Hua
    Gao, Wengui
    ADVANCED RESEARCH ON BIOCHEMICAL MATERIALS AND NANOTECHNOLOGY APPLICATION, 2013, 643 : 76 - 82
  • [6] Low-temperature complete oxidation of CO over various manganese oxide catalysts
    Dey, Subhashish
    Dhal, Ganesh Chandra
    Mohan, Devendra
    Prasad, Ram
    ATMOSPHERIC POLLUTION RESEARCH, 2018, 9 (04) : 755 - 763
  • [7] Operando mechanistic studies of selective oxidation of glycerol to dihydroxyacetone over amorphous cobalt oxide
    Truong-Giang Vo
    Ho, Po-Yun
    Chiang, Chia-Ying
    APPLIED CATALYSIS B-ENVIRONMENTAL, 2022, 300
  • [8] Theoretical perspective on CO oxidation over small cobalt oxide clusters
    Molavi, R.
    Safaiee, R.
    Sheikhi, M. H.
    Hassani, N.
    CHEMICAL PHYSICS LETTERS, 2021, 767
  • [9] OXIDE CATALYSTS FOR LOW-TEMPERATURE CO OXIDATION
    HOFLUND, GB
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1989, 198 : 123 - COLL
  • [10] Kinetic and mechanistic study of CO oxidation over nanocomposite Cu-Fe-Al oxide catalysts
    Fedorov, Aleksandr
    Saraev, Andrey
    Kremneva, Anna
    Selivanova, Aleksandra
    Vorokhta, Mykhailo
    Smid, Bretislav
    Bulavchenko, Olga
    Yakovlev, Vadim
    Kaichev, Vasily
    CHEMCATCHEM, 2020, 12 (19) : 4911 - 4921
12345