Synthesis and Complexing Properties of Novel Crown Ethers and Thiacrown Ethers Incorporating New Heterocyclic Moieties

被引：1
|
作者：
Bakavoli, Mehdi [1 ]
Rahimizadeh, Mohammad [1 ]
Rezaei-Seresht, Esmaeel [2 ]
Esfahani, Majid Mokaber [1 ]
Ziaee, Parisa [1 ]
机构：
[1] Ferdowsi Univ Mashhad, Dept Chem, Sch Sci, Mashhad 917751436, Iran
[2] Sabzevar Tarbiat Moallem Univ, Sch Sci, Dept Chem, Sabzevar, Iran
来源：
PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS | 2010年 / 185卷 / 10期
关键词：
Complexing properties; crown ether; pyridopyridazine; quinoxalines; thiacrown ether; COORDINATION CHEMISTRY; MACROCYCLIC POLYETHERS; CYCLIC POLYETHERS; METAL-SALTS; SULFIDES; CATIONS; SODIUM; IONS;
D O I：
10.1080/10426500903544280
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The synthesis of some novel crown and thiacrown ethers via the reaction of 2,3-bis(4-hydroxyphenyl) or 2,3-bis(4-mercaptophenyl)quinoxalines and pyridopyridazine with diethylene and triethylene glycol ditosylate is described. The complexing ability of compounds 5b and 5h, as the representatives of both groups of compounds, with alkali and alkali earth metal cations were measured by the solvent extraction method. The results showed that crown ether 5b comparatively had more affinity towards the Mg2+ cation, while thiacrown ether 5h had greater affinity towards the Ca2+ cation.
引用
收藏
页码：2152 / 2158
页数：7
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