Red long-lasting phosphorescence (LLP) in β-TCP type Ca9.5Mn(PO4)7 compounds

被引：23
|
作者：
Lecointre, A. [1 ]
Benhamou, R. Ait [1 ,2 ]
Bessiere, A. [1 ]
Wallez, G. [1 ]
Elaatmani, M. [2 ]
Viana, B. [1 ]
机构：
[1] Chim Paristech, Lab Chim Matiere Condensee Paris, UPMC, Coll France UMR CNRS 7574, F-75231 Paris 05, France
[2] Fac Sci Semlalia Marrakech, Lab Matiere Condensee & Environm, Marrakech 4000, Morocco
来源：
OPTICAL MATERIALS | 2011年 / 34卷 / 02期
关键词：
Phosphate compounds; Divalent manganese; Persistent luminescence; Thermally stimulated luminescence; TRICALCIUM PHOSPHATE; PERSISTENT LUMINESCENCE; CE3+; SPECTROSCOPY; IONS; EU2+;
D O I：
10.1016/j.optmat.2011.05.020
中图分类号：
T [工业技术];
学科分类号：
08 ;
摘要：
Mn-ion doped calcium phosphates namely Ca-5(PO4)(3)(OH) hydroxyapatite (HAP), beta-Ca-3(PO4)(2) (beta-TCP) as well as Ca9.5Mn(PO4)(7) whitlockite were synthesized and the optical properties of the Mn2+ cations were investigated. Annealing under reducing atmosphere enhances the emission of the divalent manganese species. Electron paramagnetic resonance (EPR) and optical spectroscopies confirm that Mn2+ ions are the active species. Orange and red emissions occur respectively for the Mn:HAP and Mn:TCP. For this latter, long-lasting phosphorescence (LLP) coming from the Mn2+ emission (T-4(1) -> (6)A(1) transition) is observed at 640 nm but it appears that the traps depths are either two shallow or too deep to lead to an efficient long-lasting emission. (C) 2011 Elsevier B.V. All flights reserved.
引用
收藏
页码：376 / 380
页数：5
相关论文
共 50 条
  • [1] Blue and red long lasting phosphorescence (LLP) in β-Zn3(PO4)2:Mn2+ ,Zr4+
    Wang, J
    Su, Q
    Wang, SB
    JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 2005, 66 (07) : 1171 - 1176
  • [2] Green and red long lasting phosphorescence (LLP) in γ-Zn3(PO4)2:Mn2+/Ga3+
    Liu, Ziran
    Zhong, Ruixia
    JOURNAL OF ALLOYS AND COMPOUNDS, 2013, 556 : 6 - 11
  • [3] Phosphorescence properties and energy transfer of red long-lasting phosphorescent (LLP) material β-Zn3(PO4)2:Mn2+, Pr3+
    Xie Ting
    Guo Hongxu
    Zhang Junying
    Odetola, Christopher
    He Yuneng
    Lin Heng
    Chen Guoliang
    Zheng Zishan
    JOURNAL OF RARE EARTHS, 2015, 33 (10) : 1056 - 1063
  • [4] Phosphorescence properties and energy transfer of red long-lasting phosphorescent(LLP) material β-Zn3(PO4)2:Mn2+,Pr3+
    谢婷
    郭鸿旭
    张俊英
    Christopher Odetola
    何裕能
    林珩
    陈国良
    郑子山
    Journal of Rare Earths, 2015, 33 (10) : 1056 - 1063
  • [5] Photostimulated red long-lasting phosphorescence in β-Zn3 (PO4)2:Mn2+,Ga3+
    Wang, J
    Su, Q
    Wang, SB
    ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (07) : J23 - J25
  • [6] The role of excess Zn2+ ions in improvement of red long lasting phosphorescence (LLP) performance of β-Zn3(PO4)2:Mn phosphor
    Wang, J
    Wang, SB
    Su, Q
    JOURNAL OF SOLID STATE CHEMISTRY, 2004, 177 (03) : 895 - 900
  • [7] Ca10.5 − xPbx(PO4)7 and Ca9.5 − xPbxM(PO4)7 ferroelectrics with the whitlockite structure
    D. V. Deyneko
    S. Yu. Stefanovich
    A. V. Mosunov
    O. V. Baryshnikova
    B. I. Lazoryak
    Inorganic Materials, 2013, 49 : 807 - 812
  • [8] Ca10.5-xPbx(PO4)7 and Ca9.5 - xPbxM(PO4)7 Ferroelectrics with the Whitlockite Structure
    Deyneko, D. V.
    Stefanovich, S. Yu.
    Mosunov, A. V.
    Baryshnikova, O. V.
    Lazoryak, B. I.
    INORGANIC MATERIALS, 2013, 49 (08) : 807 - 812
  • [9] A novel red long lasting phosphorescent (LLP) material β-Zn3(PO4)2:Mn2+, Sm3+
    Wang, J
    Su, Q
    Wang, SB
    MATERIALS RESEARCH BULLETIN, 2005, 40 (04) : 590 - 598
  • [10] Luminescence Properties of Red Long-Lasting Phosphorescence Phosphor AlN:Mn2+
    Zhang, Haoran
    Zheng, Mingtao
    Lei, Bingfu
    Liu, Yingliang
    Xiao, Yong
    Dong, Hanwu
    Zhang, Yichong
    Ye, Shuiping
    ECS JOURNAL OF SOLID STATE SCIENCE AND TECHNOLOGY, 2013, 2 (07) : R117 - R120
12345