Synthesis and crystal structure of a novel one-dimensional cyano-bridged chain complex [Sm(DMA)2(H2O)4Fe(CN)6 •5H2O]n

被引：0

作者：

Yan, B ^{[1
]}

Chen, ZD

Wang, SX

机构：

[1] Peking Univ, Coll Chem & Mol Engn, State Key Rare Earth Mat Chem & Applicat, Beijing 100871, Peoples R China

[2] Peking Univ, Univ Hong Kong Joint Lab Rare Earth Mat & Bioinor, Beijing 100871, Peoples R China

[3] Jining Teachers Coll, Dept Chem, Jining 272125, Peoples R China

来源：

ACTA CHIMICA SINICA | 2000年 / 58卷 / 12期

关键词：

cyano - bridged complex; one - dimensional chain; synthesis; crystal structure;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

Using K3Fe(CN)(6), N, N - dimethylacetamide (DMA) and Sm(NO3)(3). 6H(2)O, the title complex [Sm(DMA)(2)( H2O)(4)Fe(CN)(6). 5H(2)O](n) has been synthesized and characterized with elemental analysis, IR spectra and X - ray crystal structure. The complex crystallizes in the monoclinic P2(1)/c space group, with lattice parameters a=1.02744(14)nm, b =1.6732(2)nm, c = 1.7323(2)nm, beta =97.385(3)degrees, Z =4, R-1 =0.0412.

引用

页码：1636 / 1640

页数：5

共 5 条

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