Use of organomanganese reagents in organic synthesis

被引：60

作者：

Oshima, K ^{[1
]}

机构：

[1] Kyoto Univ, Grad Sch Engn, Dept Chem Mat, Sakyo Ku, Kyoto 6068501, Japan

来源：

JOURNAL OF ORGANOMETALLIC CHEMISTRY | 1999年 / 575卷 / 01期

关键词：

organomanganese reagents; bromine-manganese exchange; radical cyclization; addition reaction;

D O I：

10.1016/S0022-328X(98)00967-X

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Three types of reactions with organomanganate have been examined. The first topic is a reaction of gem-dibromo compounds such as gem-dibromocyclopropane and dibromomethyltrialkylsilane with trialkylmanganates(II). The reaction was initiated by bromine-manganese exchange. The second reaction is a radical cyclization of iodophenyl allyl ether and 2-iodoethanal acetal by means of trialkylmanganate(II). The third topic is an addition of allylmanganate to a carbon-carbon triple bond. A catalytic version of these reactions is also disclosed. (C) 1999 Elsevier Science S.A. All rights reserved.

引用

页码：1 / 20

页数：20

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