CO oxidation catalyzed by RuO2 nanoparticles supported on mesoporous Al2O3 prepared via atomic layer deposition

被引:3
|
作者
Kim, Il Hee [1 ]
Jeong, Myung-Geun [1 ]
Han, Sang Wook [1 ]
Park, Eun Ji [1 ]
Hwang, Young Kyu [2 ]
Kim, Young Dok [1 ,2 ]
机构
[1] Sungkyunkwan Univ, Dept Chem, Suwon 440746, South Korea
[2] KRICT, Res Ctr Nanocatalysts, Daejeon 305600, South Korea
关键词
Ruthenium oxide; CO oxidation; Atomic layer deposition; Mesoporous Al2O3; AMBIENT-PRESSURE XPS; INFRARED-SPECTROSCOPY; RUTHENIUM CATALYSTS; ROOM-TEMPERATURE; CARBON-MONOXIDE; SURFACE; DEACTIVATION; OXIDE; IDENTIFICATION; REACTIVITY;
D O I
10.1016/j.cap.2016.07.015
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
Using atomic layer deposition (ALD), RuO2 was deposited on mesoporous Al2O3 with a mean pore size of similar to 12 nm and particle diameter of similar to 1 mm. The entire internal structure of mesoporous Al2O3 was coated by RuO2 nanostructures using ALD, forming a mesoporous bead of RuO2/Al2O3. Substantially high CO oxidation activity at reaction temperatures below 100 degrees C is also shown. There was a decrease in CO oxidation activity with time at 100 degrees C, and post-annealing at 700 degrees C fully recovered the catalytic activity of fresh RuO2/Al2O3. The RuO2/Al2O3 can be useful as an oxidation catalyst for eliminating harmful molecules. (C) 2016 Elsevier B.V. All rights reserved.
引用
收藏
页码:1407 / 1412
页数:6
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