Saturated versus unsaturated: Ligand addition to the saturated metal site in an unsaturated binuclear metal complex

被引：5
|
作者：
Adams, Richard D. [1 ]
Captain, Burjor [1 ]
机构：
[1] Univ S Carolina, Dept Chem & Biochem, Columbia, SC 29208 USA
来源：
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2007年 / 46卷 / 30期
关键词：
ligand addition; phosphorus; rhenium; structure elucidation;
D O I：
10.1002/anie.200701370
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
(Chemical Equation Presented) Pretty vacant: The unsymmetrical complex 1 contains one saturated 18-electron rhenium atom and one unsaturated 16-electron rhenium atom with a vacant coordination site. CO and NCMe can add to 1 to yield complexes in which both metal atoms have 18-electron configurations. Surprisingly, the added ligands are coordinated to the metal atom in 1 that originally had the 18-electron configuration. © 2007 Wiley-VCH Verlag GmbH & Co. KGaA.
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页码：5714 / 5716
页数：3
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