High-Tc superconductivity in the new weak-ferromagnetic superconductor RuCa2PrCu2O8+δ

Superconducting onset T-c similar to 39 K below the magnetic ordering temperature T-m similar to 49 K is observed in the new magnetic superconductor RuCa2PrCu2O8+delta. This compound is crystallized with the orthorhombic distortion of the tetragonal RuSr2GdCu2O8+delta-type structure (space group P4/mmm, T-m similar to 136 K, T-c(max) similar to 65 K). With similar RuO6 octahedral and CuO5 pyramidal units, superconductivity from the Cu-O bi-layers is apparently coexisting with the very weak ferromagnetic order. Low temperature anomalous magnetic properties observed in both field-cooled (FC) and zero-field-cooled (ZFC) modes are closely related to the complex interplay and coexistence between weak ferromagnetic order and superconductivity as well as from structural distortion and sensitive sample oxygen concentration variation. On the other hand, the tetragonal RuSr2PrCu2O8+delta compound is non-superconducting and shows spin-glass-like behavior at low temperature.