The invention of radical reactions .37. A convenient radical synthesis of dialkyl diselenides from carboxylic acids.

被引：18
|
作者：
Barton, DHR
Fontana, G
机构：
[1] Department of Chemistry, Texas A and M University, College Station
来源：
TETRAHEDRON | 1996年 / 52卷 / 34期
关键词：
D O I：
10.1016/0040-4020(96)00665-5
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new and convenient synthesis of dialkyl diselenides from carboxylic acids by Barton PTOC ester based radical chemistry is described. This method was especially successful when O-cholestan-3 beta-yl-2,2,2-tricholoroselenoacetate and O-neopentyl selenobenzoate were used as radical traps. Copyright (C) Elsevier Science Ltd
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页码：11163 / 11176
页数：14
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