4-Fluoroanilinium tetrachloridoferrate(III) 18-crown-6 clathrate

被引:3
|
作者
Ge, Jia-Zhen [1 ]
Zhao, Min-Min [1 ]
机构
[1] Southeast Univ, Ordered Matter Sci Res Ctr, Coll Chem & Chem Engn, Nanjing 211189, Peoples R China
关键词
D O I
10.1107/S160053681002009X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The reaction of 4-fluoro-aniline hydro-chloride, 18-crown-6 and ferric chloride in methano-lic solution yields the title compound, (C6H 7FN)[FeCl4]·C12H24O 6, which has an unusual supramolecular structure. N-H⋯O hydrogen-bonding inter-actions between the NH3+ substituents of the 4-fluoro-anilinium cations and the O atoms of the crown ether molecules result in a rotator-stator-like structure.
引用
收藏
页码:M739 / U287
页数:11
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