Rhodium-Catalyzed Oxidative Olefination of C-H Bonds in Acetophenones and Benzamides

被引：404

作者：

Patureau, Frederic W. ^{[1
]}

Besset, Tatiana ^{[1
]}

Glorius, Frank ^{[1
]}

机构：

[1] Univ Munster, Inst Organ Chem, D-48149 Munster, Germany

来源：

ANGEWANDTE CHEMIE-INTERNATIONAL EDITION | 2011年 / 50卷 / 05期

关键词：

amination; Heck reaction; olefination; rhodium; stilbenes; PD(II)-CATALYZED OLEFINATION; AROMATIC KETONES; DIRECT ARYLATION; BENZOIC-ACIDS; ACTIVATION; FUNCTIONALIZATION; ALKYNES; ALKENYLATION; INDOLES; ARENES;

D O I：

10.1002/anie.201006222

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A good neighborhood! The metal-catalyzed oxidative C-H functionalization of electron-rich arenes is well-established, but analogous reactions of electron-poor substrates are rare. A new application makes use of common electron-withdrawing functional groups (COMe, CONH2, CONEt 2) in the rhodium-catalyzed oxidative Heck reaction to generate complex organic molecules. Cp= Î·5-C5Me 5. © 2010 Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim.

引用

页码：1064 / 1067

页数：4

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