A New Tetraphosphine and Its Application in Pd-Catalyzed Suzuki Cross-Coupling Reaction

被引：7
|
作者：
Zhang, Yu [1 ]
Yi, Tao [1 ]
Wang, Kun [1 ]
Fu, Haiyan [1 ]
Chen, Hua [1 ]
Li, Ruixiang [1 ]
机构：
[1] Sichuan Univ, Coll Chem, Minist Educ, Key Lab Green Chem & Technol, Chengdu 610064, Peoples R China
来源：
CHINESE JOURNAL OF ORGANIC CHEMISTRY | 2012年 / 32卷 / 04期
关键词：
catalysis; palladium; tetraphosphine; Suzuki cross-coupling; phenylboronic acid; ARYL HALIDES; ARYLBORONIC ACIDS; HETEROCYCLIC CARBENES; HECK VINYLATION; ALKYL BROMIDES; COMPLEXES;
D O I：
10.6023/cjoc1108181
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A new tetraphosphine, N,N,N',N'-tetra(diphenylphosphinomethyl)-cyclohexane-1,2-diamine (1) has been designed and synthesized from the commercially available cyclohexane-1,2-diamine as starting material. This tetraphosphine in combination with [Pd(eta(3)-C3H5)Cl](2) is a very efficient catalyst for Suzuki cross-coupling reaction. Various aryl- and heteroaryl-chlorides as well as aryl-, heteroaryl-, and alkyl-bromides could be successfully transformed to the desired products in up to 99% yield with 0.1 mol% catalyst loading.
引用
收藏
页码：790 / 793
页数：4
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