Fabrication of Polyethylcyanoacrylate Hollow Nanofibers

被引：0
|
作者：
Zhang Liang [1 ,2 ]
Li Xiaofeng [2 ]
Wang Dongrui [1 ]
Zhao Ning [2 ]
Dang Zhimin [1 ]
Xu Jian [2 ]
机构：
[1] Univ Sci & Technol Beijing, Sch Chem & Biol Engn, Beijing 100083, Peoples R China
[2] Chinese Acad Sci, Inst Chem, Lab Polymer Phys & Chem, Beijing 100190, Peoples R China
来源：
CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE | 2015年 / 36卷 / 01期
基金：
中国博士后科学基金; 中国国家自然科学基金;
关键词：
Ethyl cyanoacrylate; Nanofiber; Polymer; Hollow structure; VAPOR-DEPOSITION; NANOWIRE ARRAYS; POLYMER; GROWTH; FIBERS;
D O I：
10.7503/cjcu20140655
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Poly(ethyl a-cyanoacrylate) (PECA) hollow nanofibers were fabricated directly by means of one-pot monomer solution casting method. The diameter of the PECA nanofibers was 50-100 nm. The whole process was simple, rapid and took place at room temperature. Three solution systems ECA/TiCl4/CHCl3, ECA/HCl/acetone and ECA/HCOOH/CHCl3 were investigated to study the influence on the morphology and size of the achieved PECA nanofibers. The mechanism of the formation of the nanofibers were proposed. By adjusting the solution system and environment, PECA with different morphology could be obtained. The PECA fibers were hydrophobic. This method not only can be used on flat surfaces, but also on surfaces with rough structures. The PECA fiber-structured coatings could offer substrates hydrophobic ability.
引用
收藏
页码：195 / 200
页数：6
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