CO2-Catalysed aldol condensation of 5-hydroxymethylfurfural and acetone to a jet fuel precursor

被引：0
|
作者：
Lee, Roland [1 ]
Vanderveen, Jesse R. [1 ]
Champagne, Pascale [2 ]
Jessop, Philip G. [1 ]
机构：
[1] Queens Univ, Dept Chem, Kingston, ON K7L 3N6, Canada
[2] Queens Univ, Dept Civil Engn, Kingston, ON K7L 3N6, Canada
来源：
GREEN CHEMISTRY | 2016年 / 18卷 / 19期
基金：
加拿大自然科学与工程研究理事会;
关键词：
BIOMASS; CONVERSION; DEHYDRATION; BIOFUELS; SOLVENTS;
D O I：
10.1039/c6gc01697a
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
CO2 can act as a catalyst for the production of bio-jet fuel precursors through aldol condensation. CO2-Catalysed aldol condensation of HMF with acetone gives a > 95% yield of [4-(5-hydroxymethyl-2-furyl)-3-butenone] mono-aldol condensate, while direct conversion of glucose to the same mono-aldol condensate gave a yield of 11%.
引用
收藏
页码：5118 / 5121
页数：4
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