The copolymerization behaviour of diallyl maleate towards acceptor-donor monomers

被引：0
|
作者：
Krause, T [1 ]
Schmidt-Naake, G [1 ]
机构：
[1] Tech Univ Clausthal, Inst Tech Chem, D-38678 Clausthal Zellerfeld, Germany
来源：
ANGEWANDTE MAKROMOLEKULARE CHEMIE | 1998年 / 258卷
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中图分类号：
O63 [高分子化学（高聚物）];
学科分类号：
070305 ; 080501 ; 081704 ;
摘要：
The copolymerisation behaviour of diallylmaleate (DAM) with methyl methacrylate (MMA), N-phenylmaleimide (NPI), and styrene (S) in radical polymerisation was studied under the aspect of interaction of monomers with high and low electron density vinyl groups. The system DAM/S showed some indications for interaction. Generally, the strong control of degradative chain transfer could be recognised in polymerisation. A huge increase of the molecular mass is observed at low parts of DAM in the monomer composition.
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页码：83 / 86
页数：4
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