Alkenes in [2+2+2] Cycloadditions

被引：110
|
作者：
Dominguez, Gema [1 ]
Perez-Castells, Javier [1 ]
机构：
[1] Univ San Pablo CEU, Dept Chem & Biochem, E-28668 Madrid, Spain
来源：
CHEMISTRY-A EUROPEAN JOURNAL | 2016年 / 22卷 / 20期
关键词：
alkenes; cyclotrimerization; heterocycles; homogeneous catalysis; transition metals; PALLADIUM-CATALYZED CYCLOCOTRIMERIZATION; GASEOUS ALKYNE EQUIVALENTS; LIQUID ENOL ETHERS; N-H ACTIVATION; ENANTIOSELECTIVE CONSTRUCTION; CHEMOSELECTIVE COCYCLOTRIMERIZATION; REGIOSELECTIVE CYCLOTRIMERIZATION; CARBOCYCLIZATION REACTIONS; STEREOSELECTIVE-SYNTHESIS; COBALT METALLOCYCLES;
D O I：
10.1002/chem.201504987
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Participation of alkenes and allenes in [2+2+2] cycloaddition reactions has attracted much attention recently. This version of the well-established alkyne cyclotrimerization renders interesting products, such as cyclohexadienes and other polycycles, through cascade processes. Many mechanistic variations are observed when using certain metal complexes as catalysts. The frequent generation of stereogenic centers has prompted the development of efficient asymmetric versions. This Minireview summarizes the efforts reported to date on the use of double bonds as partners in [2+2+2] cyclotrimerizations.
引用
收藏
页码：6720 / 6739
页数：20
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