New contact device for separation of hydrogen isotopes in the water-hydrogen system

被引:3
|
作者
Rastunova, IL [1 ]
Rozenkevich, MB [1 ]
机构
[1] D Mendeleyev Univ Chem Technol Russia, Moscow 125047, Russia
关键词
D O I
10.13182/FST05-A895
中图分类号
TL [原子能技术]; O571 [原子核物理学];
学科分类号
0827 ; 082701 ;
摘要
A contact device of a new type - a sulfonic cation resin membrane (Nafion type) contact device for separating isotopes of hydrogen in the water-hydrogen system is represented Its main feature is space separation of hydrogen and liquid water flows that allows using non-hydrophobic catalysts for realizing the process. Results of research on the isotope exchange efficiency carried out for model protium-deuterium system have been represented. Mass exchange efficiency dependencies on temperature (T=333-413 K), pressure (P=0.1-0.4 MPa), the hydrogen flow rate (GH(2)=20-120 NL/h) have been investigated for both hydrophobic and hydrophilic catalysts. High efficiency of membrane contact devices is noted in carrying out the chemical isotope exchange between hydrogen and water in the given range of conditions.
引用
收藏
页码:128 / 131
页数:4
相关论文
共 50 条
  • [1] New phase in the water-hydrogen system
    Efimchenko, V. S.
    Kuzovnikov, M. A.
    Fedotov, V. K.
    Sakharov, M. K.
    Simonov, S. V.
    Tkacz, M.
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2011, 509 : S860 - S863
  • [2] Separation setup for the light water detritiation process in the water-hydrogen system based on the membrane contact devices
    Rozenkevich, M. B.
    Rastunova, I. L.
    Prokunin, S. V.
    [J]. FUSION SCIENCE AND TECHNOLOGY, 2008, 54 (02) : 466 - 469
  • [3] SEPARATION FACTORS OF ISOTOPIC EXCHANGE-REACTIONS OF T IN SYSTEMS OF WATER-HYDROGEN SULFIDE, WATER-HYDROGEN AND AMMONIA-HYDROGEN
    ANDREEV, BM
    ZELVENSKII, YD
    UBORSKII, VV
    UKOLOV, AA
    [J]. ZHURNAL FIZICHESKOI KHIMII, 1977, 51 (07): : 1833 - 1835
  • [4] A new type separation column for the water-hydrogen isotope catalytic exchange process
    Fedorchenko, OA
    Alekseev, IA
    Trenin, VD
    [J]. FUSION ENGINEERING AND DESIGN, 2001, 58-59 : 433 - 438
  • [5] Hydrogen Humidity Control in Water-hydrogen Inner Cooled Generatorand Refrigerating Hydrogen Moisture Removal Device
    Sun Shixiong
    Yao Zhongan(Waiqaoqiao
    Power Plant)
    [J]. Electricity, 1998, (03) : 20 - 22
  • [6] Freezing points of the system water-hydrogen fluoride
    Cady, GH
    Hildebrand, JH
    [J]. JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1930, 52 : 3843 - 3846
  • [7] INSTALLATIONS FOR SEPARATION OF HYDROGEN ISOTOPES BY THE METHOD OF CHEMICAL ISOTOPIC EXCHANGE IN THE WATER - HYDROGEN SYSTEM
    ANDREEV, BM
    SAKHAROVSKY, YA
    ROZENKEVICH, MB
    MAGOMEDBEKOV, EP
    PARK, YS
    UBORSKIY, VV
    TRENIN, VD
    ALEKSEEV, IA
    FEDORCHENKO, OA
    KARPOV, SP
    KONOPLEV, KA
    [J]. FUSION TECHNOLOGY, 1995, 28 (03): : 515 - 518
  • [8] Preliminary experiments on hydrogen isotope separation by water-hydrogen chemical exchange under reduced pressure
    Sugiyama, T
    Asakura, Y
    Uda, T
    Abe, Y
    Shiozaki, T
    Enokida, Y
    Yamamoto, I
    [J]. JOURNAL OF NUCLEAR SCIENCE AND TECHNOLOGY, 2004, 41 (06) : 696 - 701
  • [9] VAPOR-LIQUID EQUILIBRIUM OF WATER-HYDROGEN CHLORIDE SYSTEM
    KAO, JTF
    [J]. JOURNAL OF CHEMICAL AND ENGINEERING DATA, 1970, 15 (03): : 362 - &
  • [10] Separation of the isotopes of hydrogen
    Collie, CH
    [J]. NATURE, 1933, 132 : 568 - 569