Synthesis of aryl trimethylstannanes from aryl halides: an efficient photochemical method

被引：23
|
作者：
Chen, Kai [1 ]
He, Pei [1 ]
Zhang, Shuai [1 ]
Li, Pengfei [1 ]
机构：
[1] Xi An Jiao Tong Univ, FIST, Ctr Organ Chem, 99 Yanxiang Rd, Xian 710054, Shaanxi, Peoples R China
来源：
CHEMICAL COMMUNICATIONS | 2016年 / 52卷 / 58期
基金：
美国国家科学基金会;
关键词：
CROSS-COUPLING REACTIONS; C-H BORYLATION; CATALYZED STANNYLATION; STILLE REACTION; SOLAR-CELLS; ALKYNES; ARYLSTANNANES; FLUORINATION; STANNANES; GERMANIUM;
D O I：
10.1039/c6cc01135g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An efficient transition-metal-free photochemical method featuring excellent functional group tolerance, mild reaction conditions and short reaction times has been discovered and developed for the synthesis of (hetero)aryl trimethylstannanes from (hetero)aryl halides. A photo-initiated radical chain mechanism was proposed based on preliminary mechanistic studies.
引用
收藏
页码：9125 / 9128
页数：4
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