Modelling the kinetics of UV/H2O2 oxidation of dichloroacetic acid

被引：5
|
作者：
Zalazar, C. S. [1 ]
Labas, M. D. [1 ]
Lovato, M. E. [1 ]
Brandi, R. J. [1 ]
Cassano, A. E. [1 ]
机构：
[1] Univ Nacl Litoral & CONICET, INTEC, RA-3000 Santa Fe, Argentina
来源：
WATER SCIENCE AND TECHNOLOGY | 2007年 / 55卷 / 12期
关键词：
dichloroacetic acid; kinetics; UV/hydrogen peroxide; water pollution;
D O I：
10.2166/wst.2007.377
中图分类号：
X [环境科学、安全科学];
学科分类号：
08 ; 0830 ;
摘要：
The intrinsic reaction kinetics of the decomposition of dichloroacetic acid (DCA) using UV/H2O2 was studied. A complete mathematical model, including the effect of the absorbed radiation intensities and H2O2 concentration was developed. The results of the kinetic measurements were analysed using a complete mathematical model of the experimental device that was used for the laboratory operation (a differential reactor inside a recycle). In this way it was expected to obtain intrinsic kinetic parameters. Experimental data agree well with theoretical predictions esmploying just two kinetic parameters derived from the proposed reaction mechanism.
引用
收藏
页码：31 / 35
页数：5
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