PPh2Me-Mediated Tandem Reaction of 2-Alkyl-2,3-butadienoates with Isothiocyanates: Formation of 2-Aminothiophenes

被引：18
|
作者：
Guan, Xiao-Yang [1 ]
Shi, Min [1 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Organ Chem, State Key Lab Organometall Chem, Shanghai 200032, Peoples R China
来源：
ACS CATALYSIS | 2011年 / 1卷 / 10期
基金：
中国国家自然科学基金;
关键词：
allenoate; isothiocyanate; 2-aminothiophene; annulation; umpolung addition; ELECTRON-DEFICIENT OLEFINS; CATALYZED 4+2 ANNULATION; HIGHLY FUNCTIONALIZED TETRAHYDROPYRIDINES; 3+2 CYCLOADDITION; NITROGEN-HETEROCYCLES; UMPOLUNG ADDITION; PHOSPHINE; 2,3-BUTADIENOATES; ALLENOATES; CYCLOPENTENES;
D O I：
10.1021/cs2003214
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
2-Aminothiophenes were obtained through a PPh2Me-mediated tandem reaction of 2-alkyl-2,3-butadienoates with isothiocyanates, which involves an annulation of 2-alkyl-2,3-butadienoates with isothiocyanates and a subsequent umpolung addition to 2-alkyl-2,3-butadienoates.
引用
收藏
页码：1154 / 1157
页数：4
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