Bis{2,2′-[ethane-1,2-diylbis(imino-ethylene)]diphenolato-κ2O,N,N′,O′}-cerium(IV) chloroform solvate

被引：5
|
作者：
Yang, Shu-Ping [1 ]
Han, Li-Jun
Wang, Da-Qi
Wang, Bo
机构：
[1] Huaihai Inst Technol, Dept Chem Engn, Lianyungang 222005, Peoples R China
[2] Huaihai Inst Technol, Dept Math & Sci, Lianyungang 222005, Peoples R China
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE | 2007年 / 63卷
关键词：
D O I：
10.1107/S160053680705101X
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title compound, [Ce(C16H18N2O2)(2)]center dot CHCl3, the Ce-IV atom has an eight-coordinate geometry involving two tetra-dentate N,N '-(2-oxidobenzyl)ethane-1,2-diamine ligands. The asymmetric unit contains one molecule of the title complex and one chloroform molecule, linked by C-H center dot center dot center dot O and N-H center dot center dot center dot Cl hydrogen bonds. These neighbouring molecules are connected by two C-H center dot center dot center dot pi interactions, and by N-H center dot center dot center dot Cl and C-H center dot center dot center dot Cl interactions, resulting in a three-dimensional network.
引用
收藏
页码：M2777 / U1351
页数：14
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