1,5-Dimethyl-4-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(thiophen-2-yl)methyl]amino}-2-phenyl-1H-pyrazol-3(2H)-one

被引:2
|
作者
Zhu, Hualing [1 ]
Ban, Litong [2 ]
Zhang, Pingping [3 ]
Zhao, Xinxin [1 ]
Ren, Junjie [1 ]
机构
[1] Tianjin Agr Coll, Dept Basic Sci, Tianjin 300384, Peoples R China
[2] Tianjin Agr Coll, Dept Agr Sci, Tianjin 300384, Peoples R China
[3] Tianjin Agr Coll, Dept Food Sci, Tianjin 300384, Peoples R China
关键词
D O I
10.1107/S1600536811002467
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, C26H23N5O2S, an intramolecular N-H center dot center dot center dot O interaction generates an S(6) ring. The essentially planar S(6) and pyrazole rings [maximum deviations = -0.0270 (14) and 0.0195 (15) angstrom, respectively] are nearly coplanar, making a dihedral angle of 3.94 (6)degrees. The S(6) ring makes dihedral angles of 23.79 (6), 78.53 (6) and 67.91 (6)degrees with the pyrazolone ring, the pyrazole ring and the benzene ring of antipyrine, respectively. The structure exhibits a thienyl-ring flip disorder with occupancy factors in the ratio 0.82:0.18.
引用
收藏
页码:O476 / U1594
页数:12
相关论文
共 50 条
  • [1] 1,5-Dimethyl-4-{[1-(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)ethyl]amino}-2-phenyl-1H-pyrazol-3(2H)-one
    Zhu, Hualing
    Shi, Jun
    Wei, Zhen
    Bai, Yanan
    Bu, Luxia
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1583 - U676
  • [2] Methyl 2-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(thiophen-2-yl)methyl]amino}-3-phenylpropionate
    Zhu, Hualing
    Zhao, Xinxin
    Wang, Zhan
    Ren, Junjie
    Zhang, Miao
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2200 - U2010
  • [3] Methyl 2-{[(2-furyl)(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)methyl]amino}acetate
    Han, Xiao
    Yang, Xiao-Dong
    Dai, Xiao-Chang
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1936 - U2102
  • [4] 3-Methyl-4-{[(3-{[(3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(phenyl)methyl]aminomethyl}benzyl)amino](phenyl) methylidene}-1-phenyl-1H-pyrazol-5(4H)-one
    Cai, Hong-Xin
    Wu, Wei-Na
    Li, Xiao-Xia
    Wang, Yuan
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O2015 - U323
  • [5] 1,5-Dimethyl-4-(1-methyl-3-oxo-3-phenylprop-1-enylamino)-2-phenyl-1H-pyrazol-3(2H)-one
    Zhu, Hualing
    Wang, Zhan
    Ren, Junjie
    Zhang, Miao
    Xu, Wei
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2011, 67 : O1640 - U280
  • [6] 1,5-dimethyl-4-[(5-methyl-2-furyl)-methyleneamino]-2-phenyl-1H-pyrazol-3(2H)-one
    Guo, Yaning
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2008, 64 : O1170 - U3005
  • [7] 1,5-Dimethyl-4-[(2-oxo-2,3-dihydro-1H-indol-3-ylidene)amino]-2-phenyl-1H-pyrazol-3(2H)-one monohydrate
    Sun, Yi-Feng
    Li, Ji-Kun
    Zheng, Zao-Bao
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2007, 63 : O2520 - O2521
  • [8] 4-{[3,4-Dihydro-5-methyl-3-oxo-2-phenyl-2H-pyrazol-4-ylidene](phenyl)methylamino}-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one
    Wang, JL
    Yang, Y
    Zhang, X
    Miao, FM
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2003, 59 : O430 - O432
  • [9] N-[(3-Methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene)(phenyl)methyl]glycine ethyl ester
    Zhang, X
    Zhu, HL
    Xu, HZ
    Dong, M
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS, 2004, 60 : O1157 - O1158
  • [10] Methyl 2-{1-[(Z)-3-methyl-5-oxo-1-phenyl-4,5-dihydro-1H-pyrazol-4-ylidene]ethylamino}-3-phenylpropanoate
    Zhu, Hualing
    Shi, Jun
    Wei, Zhen
    Dai, Ronghua
    Zhang, Xin
    [J]. ACTA CRYSTALLOGRAPHICA SECTION E-STRUCTURE REPORTS ONLINE, 2010, 66 : O1352 - U938