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Electrochemical performance of α-MoO3-In2O3 core-shell nanorods as anode materials for lithium-ion batteries
被引:85
|作者:
Wang, Qiang
[1
]
Sun, Jing
[1
]
Wang, Qi
[1
]
Zhang, De-an
[1
]
Xing, Lili
[1
]
Xue, Xinyu
[1
]
机构:
[1] Northeastern Univ, Coll Sci, Shenyang 110004, Peoples R China
基金:
中国国家自然科学基金;
关键词:
NEGATIVE-ELECTRODE MATERIAL;
HIGH-CAPACITY;
INDIUM OXIDE;
BINDER-FREE;
STORAGE;
IN2O3;
NANOPARTICLES;
NANOSHEETS;
NANOBELTS;
FILM;
D O I:
10.1039/c5ta00127g
中图分类号:
O64 [物理化学(理论化学)、化学物理学];
学科分类号:
070304 ;
081704 ;
摘要:
alpha-MoO3-In2O3 core-shell nanorods were prepared by a facile two-step hydrothermal method. As the anode of lithium-ion batteries, their reversible capacity was up to 1304 mA h g(-1) at 0.2 C rate ( 5 hours per half cycle) and maintains 1114 mA h g(-1) after 50 cycles. At a rate of 0.3 C, 0.5 C, 1 C and 2 C, the discharge capacities after 50 cycles were maintained at 938, 791, 599 and 443 mA h g(-1), respectively. The enhanced electrochemical performance can be ascribed to the synergistic effect between alpha-MoO3 and In2O3, one-dimensional core-shell nanostructures, short paths for lithium diffusion and interface spaces.
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页码:5083 / 5091
页数:9
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