DABCO-Mediated C-O Bond Formation from Csp2-Halogen Bond-Containing Compounds and Alkyl Alcohols

被引：13

作者：

Wu, Han-Qing ^{[1
]}

Luo, Shi-He ^{[1
,2
]}

Cao, Liang ^{[1
,2
]}

Shi, Hao-Nan ^{[1
]}

Wang, Bo-Wen ^{[1
]}

Wang, Zhao-Yang ^{[1
,2
]}

机构：

[1] South China Normal Univ, Key Lab Theoret Chem Environm, Sch Chem & Environm, Guangzhou 510006, Guangdong, Peoples R China

[2] South China Univ Technol, Sch Chem & Chem Engn, Key Lab Funct Mol Engn Guangdong Prov, 381 Wushan Rd, Guangzhou 510640, Guangdong, Peoples R China

来源：

ASIAN JOURNAL OF ORGANIC CHEMISTRY | 2018年 / 7卷 / 12期

关键词：

C-O bond formation; organic halides; alcohols; 2(5H)-furanones; synthetic methods; VISIBLE-LIGHT-PHOTOREDOX; BIOLOGICAL EVALUATION; ASYMMETRIC-SYNTHESIS; ACETOXY ALLENOATES; ACID; DERIVATIVES; GENERATION; TRANSFORMATION; ANNULATIONS; ALKALOIDS;

D O I：

10.1002/ajoc.201800517

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient protocol for C-O bond formation from C-sp2-X (X=Br, Cl) bond-containing compounds and alkyl alcohols in the presence of 1,4-diazabicyclo[2.2.2]octane (DABCO) as catalyst and base under mild conditions is described. The densely functionalized 2(5H)-furanone products can be generally obtained in moderate to excellent yields via a metal-free protocol at room temperature without added solvent.

引用

页码：2479 / 2483

页数：5

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