Mercury removal and recovery from aqueous solutions by coupled complexation-ultrafiltration and electrolysis

被引：79
|
作者：
Barron-Zambrano, J [1 ]
Laborie, S [1 ]
Viers, P [1 ]
Rakib, M [1 ]
Durand, G [1 ]
机构：
[1] Ecole Cent Paris, Lab Chim & Genie Proc, F-92295 Chatenay Malabry, France
来源：
JOURNAL OF MEMBRANE SCIENCE | 2004年 / 229卷 / 1-2期
关键词：
mercury separation; complexation-ultrafiltration; electrolysis; polyethylenimine; packed bed flow-through cathode;
D O I：
10.1016/j.memsci.2003.10.028
中图分类号：
TQ [化学工业];
学科分类号：
0817 ;
摘要：
Removal of mercuric ions from wastewater by complexation-ultrafiltration using polyethylenimine (PEI) as complexing agent was previously studied. Conditions for rejection coefficients of mercury higher than 99.7% were obtained. The present work deals with the next operations: recycling of the PEI and recovery of the mercury from the concentrate of the first ultrafiltration. Direct electrodeposition of mercury using a packed bed flow-through (PBFT) cathode was carried out. Influence of operating parameters such as current intensity, pH, PEI and chloride ion concentration was studied. Depletion of mercury from 100 to 20 mg l(-1) was achieved with a current efficiency of about 100%, when the current density was 1.09 mA g(-1) of graphite. A process based on coupled complexation-ultrafiltration and electrodeposition on PBFT cathode was proposed and tested. Design elements of the whole process were given. (C) 2003 Elsevier B.V. All rights reserved.
引用
收藏
页码：179 / 186
页数：8
相关论文
共 50 条
  • [1] Mercury removal from aqueous solutions by complexation-ultrafiltration
    Barron-Zambrano, J
    Laborie, S
    Viers, PH
    Rakib, M
    Durand, G
    [J]. DESALINATION, 2002, 144 (1-3) : 201 - 206
  • [2] Removal of humic compounds from aqueous solutions by the complexation-ultrafiltration method
    Siyanitsa V.V.
    Kochkodan V.M.
    Goncharuk V.V.
    [J]. Journal of Water Chemistry and Technology, 2007, 29 (3) : 131 - 135
  • [3] Experimental study of metal ions removal from aqueous solutions by complexation-ultrafiltration
    Mimoune, Scheherazade
    Amrani, Farouk
    [J]. JOURNAL OF MEMBRANE SCIENCE, 2007, 298 (1-2) : 92 - 98
  • [4] Removal of silver from aqueous solutions by complexation-ultrafiltration using anionic polyacrylamide
    Desai, Kartik R.
    Murthy, Z. V. P.
    [J]. CHEMICAL ENGINEERING JOURNAL, 2012, 185 : 187 - 192
  • [5] Recovery of Tungsten (VI) from Aqueous Solutions by Complexation-ultrafiltration Process with the Help of Polyquaternium
    Zeng Jianxian
    Sun Xiahui
    Zheng Lifeng
    He Qincheng
    Li Shu
    [J]. CHINESE JOURNAL OF CHEMICAL ENGINEERING, 2012, 20 (05) : 831 - 836
  • [6] Application of the hybrid complexation-ultrafiltration process for metal ion removal from aqueous solutions
    Zeng, Jianxian
    Ye, Hongqi
    Hu, Zhongyu
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2009, 161 (2-3) : 1491 - 1498
  • [7] Removal and recovery of copper from wastewater by a complexation-ultrafiltration process
    Petrov, S
    Nenov, V
    [J]. DESALINATION, 2004, 162 (1-3) : 201 - 209
  • [8] Recovery of nickel from aqueous solutions by complexation-ultrafiltration process with sodium polyacrylate and polyethylenimine
    Shao, Jiahui
    Qin, Shu
    Davidson, Joshua
    Li, Wenxi
    He, Yiliang
    Zhou, H. Susan
    [J]. JOURNAL OF HAZARDOUS MATERIALS, 2013, 244 : 472 - 477
  • [9] Simultaneous Recovery of Nickel and Cobalt from Aqueous Solutions using Complexation-Ultrafiltration Process
    Shao, Jiahui
    Qin, Shu
    Li, Wenxi
    He, Yiliang
    [J]. SEPARATION SCIENCE AND TECHNOLOGY, 2013, 48 (18): : 2735 - 2740
  • [10] Removal of zinc and nickel ions from aqueous solutions by means of the hybrid complexation-ultrafiltration process
    Korus, I
    Bodzek, M
    Loska, K
    [J]. SEPARATION AND PURIFICATION TECHNOLOGY, 1999, 17 (02) : 111 - 116
12345