High-field, multifrequency EPR study of the [Mn(OH2)6]3+ cation:: Influence of π-bonding on the ground state zero-field-splitting parameters

被引：51
|
作者：
Tregenna-Piggott, PLW
Weihe, H
Barra, AL
机构：
[1] Univ Bern, Dept Chem, CH-3000 Bern, Switzerland
[2] Univ Copenhagen, Dept Chem, DK-2100 Copenhagen, Denmark
[3] CNRS, Grenoble High Magnet Field Lab, LCMI, F-38042 Grenoble, France
来源：
INORGANIC CHEMISTRY | 2003年 / 42卷 / 25期
关键词：
D O I：
10.1021/ic0347642
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
High-field, multifrequency EPR data are presented for the alum CsMn(SO4)(2).12D(2)O, containing the [Mn(OD2)(6)](3+) cation. The data are interpreted using the conventional S = 2 spin Hamiltonian, and the following parameters determined for the data obtained below 30 K: D = -4.491(7) cm(-1), E = 0.248(5) cm(-1), g(x) = 1.981(5), g(y) = 1.993(5), g(z) = 1.988(5). Although the deviation of the MnO6 framework from idealized DO symmetry is small, the magnitude of E/D is significant. The E parameter is related to ligand field parameters derived from the optical absorption spectrum. The rhombic anisotropy is shown to arise as a consequence of the pi-anisotropic nature of the manganese(III)-water interaction.
引用
收藏
页码：8504 / 8508
页数：5
相关论文
共 26 条
  • [1] The electronic ground state of [V(urea)6]3+ probed by NIR luminescence, electronic Raman, and high-field EPR spectroscopies
    Beaulac, R
    Tregenna-Piggott, PLW
    Barra, AL
    Weihe, H
    Luneau, D
    Reber, C
    [J]. INORGANIC CHEMISTRY, 2006, 45 (08) : 3399 - 3407
  • [2] High-field EPR study of resonance-delocalized [Fe2(OH)3(tmtacn)2]2+
    Knapp, MJ
    Krzystek, J
    Brunel, LC
    Hendrickson, DN
    [J]. INORGANIC CHEMISTRY, 1999, 38 (14) : 3321 - 3328
  • [3] EPR STUDY OF LOW-SYMMETRY MN2+ CENTERS IN LINBO3 - SUPERPOSITION MODEL AND CRYSTAL-FIELD ANALYSIS OF THE ZERO-FIELD SPLITTING PARAMETERS
    YEOM, TH
    CHOH, SH
    CHANG, YM
    RUDOWICZ, C
    [J]. PHYSICA STATUS SOLIDI B-BASIC RESEARCH, 1994, 185 (02): : 417 - 428
  • [4] High-field magnetic ground state in S=1/2 kagome lattice antiferromagnet ZnCu3(OH)6Cl2
    Asaba, Tomoya
    Han, Tian-Heng
    Lawson, B. J.
    Yu, F.
    Tinsman, C.
    Xiang, Z.
    Li, G.
    Lee, Young S.
    Li, Lu
    [J]. PHYSICAL REVIEW B, 2014, 90 (06):
  • [5] EPR zero-field splitting parameters and structural distortion study of Mn2+-doped (CH3)4NCdCl3 crystal in high-temperature phases
    Dong, Die
    Kuang Xiaoy-Yu
    Guo Han-Jun
    Hui, Wang
    Zhou Kang-Wei
    [J]. CHEMICAL PHYSICS LETTERS, 2006, 426 (1-3) : 77 - 80
  • [6] EPR measurements of the spin-Hamiltonian zero-field splitting parameters as a function of temperature in Mn2+-doped Cs2NaLaCl6
    Gleason, RJ
    Boldu, JL
    Cabrera, E
    Quintanar, C
    Munoz, E
    [J]. JOURNAL OF PHYSICS AND CHEMISTRY OF SOLIDS, 1997, 58 (10) : 1507 - 1512
  • [7] High-field multifrequency ESR in the S=5/2 kagome-lattice antiferromagnet KFe3(OH)6(SO4)2
    Fujita, T.
    Yamaguchi, H.
    Kimura, S.
    Kashiwagi, T.
    Hagiwara, M.
    Matan, K.
    Grohol, D.
    Nocera, D. G.
    Lee, Y. S.
    [J]. PHYSICAL REVIEW B, 2012, 85 (09)
  • [8] COMPREHENSIVE APPROACH TO THE ZERO-FIELD SPLITTING OF 6S-STATE IONS-MN2+AND FE3+IN FLUOROPEROVSKITES
    YU, WL
    RUDOWICZ, C
    [J]. PHYSICAL REVIEW B, 1992, 45 (17) : 9736 - 9748
  • [9] Analysis of Ground-State Zero-Field Splitting for Mn2+ in ZnNbOF5•6(H2O) and CoNbOF5•6(H2O)
    Li Ju-Fen
    Kuang Xiao-Yu
    [J]. CHINESE PHYSICS LETTERS, 2011, 28 (06)
  • [10] EPR and superposition-model analysis of zero-field splitting parameters for Mn2+ doped in ZnNbOF5•6(H2O) and CoNbOF5•6(H2O) single crystals
    Rathee, S. P.
    Hooda, S. S.
    [J]. INDIAN JOURNAL OF PHYSICS, 2024,
123