Direct conversion of sulfinamides to thiosulfonates without the use of additional redox agents under metal-free conditions

被引：6

作者：

Ji, Yuan-Zhao ^{[1
]}

Zhang, Chi ^{[1
]}

Wang, Jun-Hu ^{[1
]}

Li, Hui-Jing ^{[1
,2
]}

Wu, Yan-Chao ^{[1
]}

机构：

[1] Harbin Inst Technol, Weihai Marine Organism & Med Technol Res Inst, Weihai 264209, Peoples R China

[2] Weihai Huiankang Biotechnol Co Ltd, Weihai 264200, Peoples R China

来源：

ORGANIC & BIOMOLECULAR CHEMISTRY | 2021年 / 19卷 / 42期

基金：

中国国家自然科学基金;

关键词：

SULFONYL HYDRAZIDES; FACILE SYNTHESIS; UNSYMMETRICAL THIOSULFONATES; FREE PROTOCOL; OXIDATION; THIOLS; DISULFIDES; EFFICIENT; ARYL; SULFIDES;

D O I：

10.1039/d1ob01714d

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Direct conversion of sulfinamides to thiosulfonates is described. Without the use of additional redox agents, the reaction proceeds smoothly in the presence of TFA under metal-free conditions. This protocol possesses many advantages such as odourless and stable starting materials, broad substrate scope, selective synthesis, and mild reaction conditions.

引用

页码：9291 / 9298

页数：8

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