Molecular Recognition of 1,5 Diamino Anthraquinone by p-tert-butyl-Calix(8)arene

被引:8
|
作者
Suganthi, G. [1 ]
Meenakshi, C. [2 ]
Ramakrishnan, V. [1 ]
机构
[1] Madurai Kamaraj Univ, Sch Phys, Dept Laser Studies, Madurai 625021, Tamil Nadu, India
[2] Sri Meenakshi Govt Coll Women, Dept Chem, Madurai 625002, Tamil Nadu, India
关键词
1; 5-Diaminoanthraquinone; p-tert-butyl-calix (8)arene; Molecular recognition; Host-Guest interaction; Absorption and fluorescence spectroscopy; SPECTRAL INVESTIGATIONS; COMPLEXES; 2,3-BIS(CHLOROMETHYL)-1,4-ANTHRAQUINONE;
D O I
10.1007/s10895-010-0651-z
中图分类号
Q5 [生物化学];
学科分类号
071010 ; 081704 ;
摘要
The molecular recognition properties of p-tert-butyl-calix(8)arene with 1,5 -diamino anthraquinone (1,5 DAAQ) were studied by using UV-Visible and Fluorescence spectroscopic techniques. The binding constant was determined by using the Benesi-Hilde brand expression. It was found that the host-guest complex was formed between 1,5 DAAQ and p-tert-butyl- calix(8)arene in the 1:2 Stoichiometry ratio.
引用
收藏
页码:1017 / 1022
页数:6
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