(Me2NH2)[(Ph3Sn)3(MoO4)2], a triorganotin molybdate with layer structure

被引：6
|
作者：
Kondracka, Malgorzata [1 ]
Merzweiler, Kurt [1 ]
机构：
[1] Univ Halle Wittenberg, Naturwissenschaft Fak 2, Inst Chem, D-06120 Halle, Germany
来源：
ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE | 2007年 / 633卷 / 08期
关键词：
tin; molybdate; coordination polymer; crystal structure;
D O I：
10.1002/zaac.200700163
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The reaction of [(Ph3Sn)(2)MoO4] with (Me2NH2)Cl in an acetonitrile/water mixture leads to the formation of (Me2NH2)[(Ph3Sn)(3)(MoO4)(2)] (1). (1) crystallizes in the space group Pca2(1) with a = 1967.0(4), b = 1353.1(2) and c = 2176.6(5) pm. In the crystal structure of I Ph3SnO2 bipyramides and MoO4 tetrahedra are linked by corner sharing to give a layer structure. Additionally the layers are connected by (OHN)-H-. . .-N-. . . hydrogen bridges between MoO4 groups and [Me2NH2](+) ions to give a 3D network structure.
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收藏
页码：1131 / 1133
页数：3
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