Tunable Wettability of Electrospun Polyurethane/Silica Composite Membranes for Effective Separation of Water-in-Oil and Oil-in-Water Emulsions

被引:61
|
作者
Fang, Wenyuan [1 ]
Liu, Libin [1 ]
Guo, Gailan [1 ]
机构
[1] Qilu Univ Technol, Shandong Prov Key Lab Fine Chem, Key Lab Fine Chem Univ Shandong, Jinan 250353, Shandong, Peoples R China
关键词
electrospinning; membranes; oil/water separation; polymers; surfactants; COATED MESH; OIL/WATER; SUPERHYDROPHOBICITY; EFFICIENT; FABRICATION; TRANSITION; MIXTURES; HYDROGEL; FILM;
D O I
10.1002/chem.201701409
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Polymer-dominated membranes with switchable wettability are highly desired due to their on-demand applications for oil/water separation. Herein, a low-cost methodology to fabricate membranes consisting of hyperbranched polyurethane (HBPU) and fluorine-modified silica (F-SiO2) with tunable wettability by electrospinning is reported. The HBPU/F-SiO2 composite membranes can be transformed from superhydrophobicity to -philicity through plasma treatment; these membranes exhibit different wettability for effective separation of surfactant-stabilized water-in-oil and oil-in-water emulsions.
引用
收藏
页码:11253 / 11260
页数:8
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