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Tunable Wettability of Electrospun Polyurethane/Silica Composite Membranes for Effective Separation of Water-in-Oil and Oil-in-Water Emulsions
被引:61
|作者:
Fang, Wenyuan
[1
]
Liu, Libin
[1
]
Guo, Gailan
[1
]
机构:
[1] Qilu Univ Technol, Shandong Prov Key Lab Fine Chem, Key Lab Fine Chem Univ Shandong, Jinan 250353, Shandong, Peoples R China
关键词:
electrospinning;
membranes;
oil/water separation;
polymers;
surfactants;
COATED MESH;
OIL/WATER;
SUPERHYDROPHOBICITY;
EFFICIENT;
FABRICATION;
TRANSITION;
MIXTURES;
HYDROGEL;
FILM;
D O I:
10.1002/chem.201701409
中图分类号:
O6 [化学];
学科分类号:
0703 ;
摘要:
Polymer-dominated membranes with switchable wettability are highly desired due to their on-demand applications for oil/water separation. Herein, a low-cost methodology to fabricate membranes consisting of hyperbranched polyurethane (HBPU) and fluorine-modified silica (F-SiO2) with tunable wettability by electrospinning is reported. The HBPU/F-SiO2 composite membranes can be transformed from superhydrophobicity to -philicity through plasma treatment; these membranes exhibit different wettability for effective separation of surfactant-stabilized water-in-oil and oil-in-water emulsions.
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页码:11253 / 11260
页数:8
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