Controlled Release from Core-Shell Nanoporous Silica Particles for Corrosion Inhibition of Aluminum Alloys

被引:4
|
作者
Jiang, Xingmao [1 ,2 ,3 ]
Jiang, Ying-Bing [4 ]
Liu, Nanguo [5 ]
Xu, Huifang [6 ]
Rathod, Shailendra [1 ,2 ]
Shah, Pratik [1 ,2 ]
Brinker, C. Jeffrey [1 ,2 ,7 ]
机构
[1] Univ New Mexico, Dept Chem & Nucl Engn, Albuquerque, NM 87106 USA
[2] Univ New Mexico, Ctr Microengineered Mat, Albuquerque, NM 87106 USA
[3] Lovelace Resp Res Inst, Aerosol & Resp Dosimetry Program, Albuquerque, NM 87108 USA
[4] Univ New Mexico, Transmiss Electron Microscopy Labs, Albuquerque, NM 87131 USA
[5] Dow Corning Corp, SCB Innovat Accelerator, Midland, MI 48686 USA
[6] Univ Wisconsin, Dept Geosci, Madison, WI 53706 USA
[7] Sandia Natl Labs, Adv Mat Lab, Albuquerque, NM 87185 USA
基金
美国能源部; 美国国家科学基金会;
关键词
COATINGS; CHROMATE; COMPOSITE;
D O I
10.1155/2011/760237
中图分类号
TB3 [工程材料学];
学科分类号
0805 ; 080502 ;
摘要
Cerium (Ce) corrosion inhibitors were encapsulated into hexagonally ordered nanoporous silica particles via single-step aerosol-assisted self-assembly. The core/shell structured particles are effective for corrosion inhibition of aluminum alloy AA2024-T3. Numerical simulation proved that the core-shell nanostructure delays the release process. The effective diffusion coefficient elucidated from release data for monodisperse particles in water was 1.0x10(-14) m(2)s for Ce3+ compared to 2.5x10 (13) m(2)s for NaCl. The pore size, pore surface chemistry, and the inhibitor solubility are crucial factors for the application. Microporous hydrophobic particles encapsulating a less soluble corrosion inhibitor are desirable for long-term corrosion inhibition.
引用
收藏
页数:10
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