Research progress in cation-π interactions

被引：25
|
作者：
Cheng JiaGao [2 ]
Luo XiaoMin [1 ]
Yan XiuHua [1 ]
Li Zhong [2 ]
Tang Yun [2 ]
Jiang HuaLiang [1 ,2 ]
Zhu WeiLiang [1 ,3 ]
机构：
[1] Chinese Acad Sci, Shanghai Inst Mat Med, Drug Discovery & Design Ctr, Shanghai 201203, Peoples R China
[2] E China Univ Sci & Technol, Sch Pharm, Shanghai 200237, Peoples R China
[3] E China Univ Sci & Technol, Sch Sci, Shanghai 200237, Peoples R China
来源：
SCIENCE IN CHINA SERIES B-CHEMISTRY | 2008年 / 51卷 / 08期
基金：
中国国家自然科学基金;
关键词：
cation-pi interaction; intermolecular interaction; noncovalent interaction;
D O I：
10.1007/s11426-008-0082-8
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
Cation-pi interaction is a potent intermolecular interaction between a cation and an aromatic system, which has been viewed as a new kind of binding force, as being compared with the classical interactions (e.g. hydrogen bonding, electrostatic and hydrophobic interactions). Cation-pi interactions have been observed in a wide range of biological contexts. In this paper, we present an overview of the typical cation-pi interactions in biological systems, the experimental and theoretical investigations on cation-pi interactions, as well as the research results on cation-pi interactions in our group.
引用
收藏
页码：709 / 717
页数：9
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