A semi-empirical model for density gradient in microcellular thermoplastic foams

被引:7
|
作者
Mohyeddin, Ali [1 ]
Fereidoon, Abdolhosein [1 ]
机构
[1] Semnan Univ, Dept Mech Engn, Semnan 3535119111, Iran
关键词
microcellular thermoplastic foam; solid-state batch process; polystyrene-nitrogen system; density gradient; GLASS-TRANSITION TEMPERATURE; CARBON-DIOXIDE; SURFACE-TENSION; NUCLEATION; POLYSTYRENE; ADDITIVES; PRESSURE; GROWTH;
D O I
10.1177/0021955X11406003
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
In microcellular plastics, produced by the solid-state batch method, an integral solid skin and a core with graded porosity can be created by allowing absorbed gas to diffuse from the surface of a saturated specimen prior to foaming. In this article a semi-empirical model is proposed to predict the local density of microcellular foam as a function of dissolved gas concentration. To this end, Henry's law is applied on available experimental data for polystyrene-nitrogen system. The resultant spatial variation of mass density would be interesting for analyzing engineering structures made of microcellular plastics.
引用
收藏
页码:413 / 428
页数:16
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