Intercalation of two-dimensional oxalate-bridged molecule-based magnets into layered double hydroxide hosts

被引：27

作者：

Coronado, Eugenio ^{[1
]}

Marti-Gastaldo, Carlos ^{[1
]}

Navarro-Moratalla, Efren ^{[1
]}

Ribera, Antonio ^{[1
,2
]}

Galan-Mascaros, Jose R. ^{[3
]}

机构：

[1] Univ Valencia ICMol, Paterna 46980, Spain

[2] Univ Valencia FGUV, Fdn Gen, Valencia 46010, Spain

[3] Inst Chem Res Catalonia ICIQ, Tarragona 43007, Spain

来源：

JOURNAL OF MATERIALS CHEMISTRY | 2010年 / 20卷 / 42期

关键词：

CRYSTAL-STRUCTURES; M-III; COMPLEXES; NANOSHEETS; FE; INSERTION; DESIGN; CR; MAGNETIZATION; COEXISTENCE;

D O I：

10.1039/c0jm01722a

中图分类号：

O64 [物理化学（理论化学）、化学物理学];

学科分类号：

070304 ; 081704 ;

摘要：

Here we report the intercalation of a Mn-II-Cr-III oxalate-bridged extended network into the interlamellar space offered by a Zn-II-Al-III LDH host. This material exhibits ferrimagnetic ordering below 3 K from dominant antiferromagnetic interactions between metallic centres through the oxalate linker. Our result opens the door for the design of a completely new sort of hybrid magnetic multilayers from molecule-based magnets and layered inorganic flexible hosts, where the intrinsic properties of both sub-layers can be combined.

引用

页码：9476 / 9483

页数：8

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