Novel nano-crystalline Er2O3 hydrbgen isotopes permeation barriers

Hydrogen Isotopes permeation barriers (HIPB) are used to reduce hydrogen isotopes permeation and leakage in the fields such as thermonuclear fusion energy, hydrogen energy, petroleum industry and vacuum solar receiver. In this study, nano-crystalline Er2O3 HIPB with about 5-10 nm grain size were made by sol-gel method. Their performances, including deuterium-permeation reduction factor (D-PRF), micro-structure, mechanical property and electrical property were reported. The D-PRF of 0.2 mu m nano crystalline Er2O3 HIPB reached 300 at 700 degrees C and did not deteriorate after 128 h deuterium permeation. The bonding strength and the nano-hardness steadily remained about 13 N and 10 GPa after 128 h deuterium permeation at 700 degrees C, respectively. The morphology and micro-structures of the nano-crystalline Er2O3 HIPB showed no measurable changes after 128 h deuterium permeation, which ensured the stable D-PRF and mechanical properties. However, the electrical resistivity of the nano-crystalline Er2O3 HIPB decreased after deuterium permeation at 700 degrees C. The electrical resistivity decreased from 9 x 10(9) Omega cm by over three orders of magnitude and then tended to be stable, which might be attributed to oxygen loss or deuterium invasion. (C) 2016 Elsevier Ltd. All rights reserved.