Structures of Coordination Polymers of Zinc, Cobalt(II), and Manganese(II) Trifluoroacetates with 4,4'-Dipyridyl

被引：8

作者：

Uvarova, M. A. ^{[1
]}

Nefedov, S. E. ^{[1
]}

机构：

[1] Russian Acad Sci, Kurnakov Inst Gen & Inorgan Chem, Moscow 119991, Russia

来源：

RUSSIAN JOURNAL OF INORGANIC CHEMISTRY | 2021年 / 66卷 / 12期

关键词：

trifluoromethylacetates; zinc; cobalt; manganese; coordination polymers; 1D polymer; 3D polymer; zigzag geometry; four-core metal butterfly; synthesis; X-ray diffraction; SECONDARY BUILDING UNITS; 4,4'-BIPYRIDINE; COMPLEXES; BENZOATES; DESIGN; NI;

D O I：

10.1134/S0036023621120202

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

Thermal heating of crystals [Zn-3(mu-OH2)(2)(mu-OOCCF3)(4)(OOCCF3)(2)(OH2)(2)][mu-O(CH2CH2)(2)O)], Co-3(mu-OOCF3)(4)(mu-OH2)(2)(OOCF3)(2)[O(CH2CH2)(2)O](2)(OH2)(2), and [Mn-2(mu-OOCCF3)(3)(OOCCF3) (OH2)][mu-O(CH2CH2)O](2) in vacuum (180 degrees C) leads to the formation of powders, the dissolution of which in THF followed by slow diffusion of a solution of 4,4'-dipyridyl (dipy) in THF results in the formation of 1D coordination polymer [Zn(OOCCF3)(2)(dipy) . 0.5THF](n) with a zigzag geometry and 3D coordination polymers {Co[(OOCCF3)(dipy)](2)}(n) and {Mn[(OOCCF3)(dipy)](2) . 3THF}(n), the latter containing solvate molecules THF in pores. The obtained compounds have been studied by chemical analysis, IR spectroscopy, and X-ray diffraction.

引用

页码：1837 / 1845

页数：9

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