The novel one-pot synthesis of functionalized vinyl sulfides using triphenylphosphine catalyzed nucleophilic addition of thiols to acetylenes

被引：11

作者：

Baharfar, Robabeh ^{[1
]}

Baghbanian, Seyed M. ^{[1
]}

Hossein nia, Roghayeh ^{[1
]}

Bijanzadeh, Hamid R. ^{[2
]}

机构：

[1] Univ Mazandaran, Dept Chem, Babol Sar, Iran

[2] Univ Tarbiat Modarres, Dept Chem, Tehran 141554838, Iran

来源：

LETTERS IN ORGANIC CHEMISTRY | 2007年 / 4卷 / 08期

关键词：

triphenylphosphine; alkyl propiolate; organophosphorus compounds; vinyl sulfides;

D O I：

10.2174/157017807782795547

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

3-mercapto-2-butanone undergoes a smooth reaction with electron-deficient symmetric and asymmetric acetylenes in the presence of catalytic amount of triphenylphosphine under neutral conditions to produce S-functionalized vinyl sulfides (Z/E isomers) in moderately high yields.

引用

页码：567 / 570

页数：4

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