{2,6-bis[(4R)-(+)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]pyridine-κ3N}dichlorozinc(II)

被引:3
|
作者
Panosyan, FB [1 ]
Lough, AJ [1 ]
Chin, J [1 ]
机构
[1] Univ Toronto, Dept Chem, Toronto, ON M5S 3H6, Canada
关键词
D O I
10.1107/S160053680301924X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
In the title compound, [Zn-II(Cl)(2)(C17H23N3O2)] or [Zn-II(Cl)(2)(pybox)], where pybox is 2,6-bis[(4R)-(+)-4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl]pyridine, the coordination geometry is a distorted trigonal bipyramid. The pybox exhibits tridentate coordination to Zn-II in a [1:1] ratio, with the apical positions of the bipyramid occupied by the oxazoline N atoms of the ligand. The two Cl atoms and the pyridine N atom form the trigonal base of the bipyramid.
引用
收藏
页码:M864 / M866
页数:3
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