Junction Characteristics System Based on Composite Organic Semiconductors: Polystyrene/Polyaniline Doped by [BMIM] [BF4] Ionic Liquid

被引:4
|
作者
Fetouhi, Bekhaled [1 ]
Benabdellah, Abdelkader [1 ]
Belarbi, El Habib [1 ]
Ilikti, Hocine [2 ]
Benabdallah, Tayeb [2 ]
机构
[1] Ibn Khaldoun Univ Tiaret, Synth & Catalysis Lab, Tiaret, Algeria
[2] Univ Sci & Technol Oran, Chem & Elect Lab Metall Complexes, Bir El Djir, Algeria
关键词
Polyaniline; polystyrene; ionic liquids; composite organic conductors; schottky diode; POLYMER SCHOTTKY BARRIERS; ROOM-TEMPERATURE; POLYANILINE; FILMS; CHLORIDE; DIODES; ELECTROPOLYMERIZATION; HEXAFLUOROPHOSPHATE; ELECTRODEPOSITION; NANOPARTICLES;
D O I
10.3139/113.110341
中图分类号
O69 [应用化学];
学科分类号
081704 ;
摘要
A junction of emeraldine salt (ES [BF4-]) doped by [BMIM] [BF4] may be preferred over the other junctions due to its low ideality factor and maximum rectification ratio. Schottky barrier diode based on composite of polyaniline (ES [BF4-]) with polystyrene has been created and characterized using aluminium as Schottky contact and argent as an ohmic contact. The observed current-voltage characteristics can be satisfactorily fitted using the modified Schottky equation. Capacitance-voltage (C-V) in reverse bias and current-voltage (I-V) plots indicates a rectification. Various junction parameters were calculated from the temperature dependent I-V and C-V data and discussed. These results indicate that the composite materials have better mechanical strength and diode quality compared to the pure semiconducting polymer.
引用
收藏
页码:541 / 546
页数:6
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